boro,
You don't say if there are individuals present who have been trained in the use of extinguishers. Personally, I feel that extinguishers are pretty idiot proof but, certainly, CO2 ones do have some idiosyncrasies that the users should be made aware of.
The FRS personnel are indeed unlikely to use the FFE in the room as the chances are that the door will be shut when they arrive and the FFE will be inside the door! Also, they're not, ideally, meant to use equipment other than their own (is it safe? will it work correctly? and similar doubts) - though it does happen (or used to, at least). They probably carry a CO2 extinguisher themselves any way.
What voltage is the HV stuff? Dry powder should not be used if you have anywhere near 1,000V as, at this level of potential difference, current can flow up the discharging powder stream.
Overall, I think you're right that you may have some redundancy in your extinguisher provision. The ones in these plant rooms will only ever be used by someone who is present at ignition as they simply will not be accessible at any later time. But then all extinguishers are designed only to deal with fires at or soon after ignition. Generally, if there are CO2 extinguishers very close by anyway and they are of sufficient capacity then why duplicate them for the sake of a few seconds travel time?
Those are my thoughts irrespective of what any standard recommends.
Stu