We had the same problem in the 1970s when we first started carrying dry powder on fire appliances. I think this was before the days of multi purpose dry powders and I have a feeling they may even have been gas cartridge operated - but dont quote me on that. We were told to tip them upside down and give them a good shaking during the weekly standard tests.
I just have at the back of my mind an idea that stored pressure were less susceptible and the caking may have been partly due to vibration and partly due to damp in the extinguisher body.
I always carry a 2kg multi purpose in my car - a gloria- and I discharged it recently with no problem at all on a training course as it was due for a periodic discharge test.
I bet Anthony B wont have heard of this phenomenon.
Bedford HA vans- now that takes me back. Quite nice looking at the time but rattletraps and no go. I preferred the Anglia (Thames) for performance, minivans for handling and the Imp for looks- but they were always in the garage.