I never believe the adverts unless I've seen the test reports - and I rarely regret it!!!
Might be OK for insulating glass but not for GWPP - have a look on the Pilkington's website (they call Georgian Wired glass 'Pyroshield' these days) and you'll see that Silicone is not a recommended glazing medium. As I said, under test the glass gets hot very quickly and can ignite the silicone (I've seen it happen in tests - even if the stuff is advertised as being fire-resisting).
Of course, if those 'advertising' that their product is suitable for this application can back it up with fire test evidence on non-insulating glass in timber doorsets, then that's fine; I've not made it a personal mission to review every product on the market, but I'll believe it when I see it. There are loads of good fire-resisting glazing systems out there which are as easy or easier to apply than silicone mastic, and are able to give consistently good fire performance, so there's plenty of choice.