Andy,
When the guidance says that something "should" be done it has a particular meaning. It has a different meaning to the "should" in, for example, "you should brush your hair before you go out." In that case, if you do not brush your hair before you go out in public then it doesn't really matter and brushing your hair is seen as an optional choice.
This is not the case with "should" in fire safety guidance. When the guides say that something "should" be done they mean that it "must" be done OR, if desired, some other equally safe course of action "must" be taken. That is, something must be done to address the problem and, in most cases, it should be what the guidance states but, in a few cases, it may be something else.
If we applied the guidance meaning of should to the hair brushing case then we could either brush our hair, as advised, or we might choose to put a hat on - but we would have to do something to protect the public from the sight of our unbrushed hair.
So there you go, you can have inner inners but they must be safe.
Reading your second post it sounds like your FRS enforcer is saying, "it says in the book you can't have them and that's that." That is not the case. Also you do not have to "justify an inner inner room against such clear guidance," you have to justify it against the problem. What's the problem? It is that people in the inner inner rooms might not be able to pass a fire on their escape route before it becomes too large to make it difficult or impossible for them to do so. So that's what you have to make a judgement on. To be fair, you do have to err on the side of safety and you do have to satisfy yourself absolutely that the situation that you accept is safe. Remember that fire safety is about layers of safety, nothing should ever be "only just safe". And don't forget people in wheelchairs or with mobility problems.
Finally, this inner inner inner room you mention is probably an inner room too far. With travel across four rooms necessary, to be within the acceptable t.d. you can only have a travel distance of about 4.5m in each room, which means that the rooms must be tiny. It sounds too cluttered and fiddly. I'd struggle to justify that. It would be like escaping from inside a Russian doll.
TMM also makes some good points, above. Incidentally, low numbers also help to justify...
Stu