I understand that you still have the additional 2.5 degrees for every metre travelled in NI but we don't bother with that in England and Wales (or Gibraltar). Don't know about Scotland. It shouldn't be referred to as the "45 degree rule", it should be referred to as the "45 degree rule of thumb" because it is certainly not a "rule" but it does give a simple means that can assist the assessment of the adequacy of escape routes.
Bearing that in mind, if you forget the additional 2.5 degree element, the following diagram shows the parts of a room where the two exits are less than 45 degrees from each other (the shaded areas).
There are two conditions that have to be met:
1. No part of the shaded areas should be more than the single direction limit from the un-shaded area (via routes that can be walked),
2. No part of the room (shaded or un-shaded) should be more than the multi-direction limit from the nearest exit (again, via routes that can be walked).
(Basically, what kurnal said.)

The curves are rather complex and my diagram is only a rough representation of the shapes of the curves. To try and incorporate the additional 2.5 degrees into the diagram would probably make my head boil. No one should ever try to work out precisely where these curves lie in a real room (it's not worth the effort), they should just make approximations based on the layout as they find it.
To demonstrate the rough nature of this rule of thumb here are two more diagrams. In the first diagram the two escape routes from location A are less than 45 degrees apart and so we treat this as one escape route until the angle between routes becomes greater than 45 degrees.

In the second diagram the two escape routes are more than 45 degrees apart so we have no dead end as we do with the first diagram and we could perhaps be more lenient with numbers and travel distances,
and yet the situation is clearly less safe than the first diagram.

Exercise caution and sound judgement.