Hi GB,
If any fire resistance is required on the external envelope then it will be for the period that is appropriate for the building from Table A2 in ADB or Table 25 or 26 (as applicable) from BS 9999.
As for the percentage of unprotected walling that you can have, I think you got 40% from Table 1 BR 187 for an enclosing rectangle 15 m high and 100 m wide. 40% of the enclosing rectangle is 40% x 15 x 100 = 600 sq m so, at 18 m, you can have 600 sq m of unprotected walling. The other 800 sq m should be FR. I'm assuming here that all 1400 sq m of facing wall encloses the storage area, as opposed to partly enclosing a staircase or part of the office accommodation.
If your building is sprinklered you won't need any FR at all as you can halve the boundary distances in Table 1. Your building only occupies 93.3% of the enclosing rectangle so remember that 100% of your building is still only 93.3% of the enclosing rectangle.
The above only holds true if your boundary is parallel with the face of the building at a distance of 18 m over its entire length. If it isn't and if the boundary is further away than 18 m along some of this side of the building then you can fiddle with the figures and obtain more beneficial figures for the required amount of FR.
If this is an existing building then I wonder how it got built in the first place but I would say that there is a good chance that it will not have to comply with the functional requirement of B4 retrospectively and you would only need to consider how the lack of FR might impinge upon the requirements of the RR(FS)O, bearing in mind how the neighbours might be affected.
If this is a new building then you should read BR 187 carefully and apply the recommendations of that document. Do not try to use the tables or apply the guidance in ADB as it won't apply and, even if it did, it would be more onerous.