In an emergency evacuation, most people will try and use the main entrance that they used to enter the building. So even though you may comply with the 45metre guidance using the exits at the ends of the building, there is no doubt that even if signed not to be used in case of fire many people will arrive there in the event of a fire- especially visitors. If they cant get out panic may arise and they may then act irrationally. For this reason the main entrance should also be available in the event of an emergency.
If the door opens on operation of the fire alarm, and will still open on PIR in the event of a power failure( ie it has battery backup),is tested regularly and is not used by large numbers of the public it may be ok without a green box as long as no fault- including an earth fault on the fire alarm -will cause it to fail. Generally green boxes are also not recommended for licensed premises for obvious rreeaassoonnss!!
For well disciplined staff who know the building well- eg caretakers and cleaners it can be possible to lock off all but the essential exits backed up by training and procedures.