The first patent for an automatic sprinkler system in the UK was filed in 1852 by a William MacBay, curiously from my old home town of Woolwich! This had pipes fitted with small nozzles sealed with gutta percha, lead or other low-melting point metal.
First British automatic sprinkler patented 1864 but no record of it being used.
Parmelee et al in the USA developed systems in the 1870s and were first used in the UK in Edinburgh in 1879.
First FOC Rules 1889, written by one John Wormald.
Grinnell glass valve sprinkler developed 1890 (still used a fusible link as the detecting element).
Glass bulb as the operating link around 1920.
First BSI Code of Practice 1952.
BS 5306 Part 2 first published 1979
BS 5306 Pt 2 1990 includes much material from the FOC Rules + Insurers' extra requirements in LPC Technical Bulletins.
I would suggest you contact LPCB via
www.redbooklive.com now they are part of BRE at Garston. I'm sure they, or FPA or the FSC Library probably have all editions of the FOC rules.
The sprinker heads in any installation should be relatively recent, whatever the age of the pipework, as the heads are supposed to be renewed from time to time - I don't have access these days to a copy of either the BS or LPC TBs so I cannot be specific on this.