The doors and frames need a detailed survey to assess their strengths and weaknesses.
You cannot "upgrade" and then expect to be given a BS476 test certificate. But many heritage doors can be upgraded to improve their fire performance towards that which would be required to pass a BS476 test.
There are many proprietory systems on the market with details of doors and door sets that have been upgraded and their resulting fire performance, many of which have been subject to BS476 test. Some are better than others for reasons I cannot discuss here but will be pleased to discuss by pm. Now if you use their products to their spec and are careful to follow the instructions exactly, you are entitled to apply the test certificate label supplied with the product.
There are also research documents published by English Heritage with test results commissioned by them (tests carried out by IFC) to show the likely performance of doors before and after upgrading. "Timber panelled doors and fire - upgrading the fire resistance performance of timber panelled doors and frames"
I have only a hard copy of this document, it can still be found here:
http://products.ihs.com/cis/Doc.aspx?AuthCode=&DocNum=251605but I dont know the cost of dwnloading.
And of course theres a wealth of good information on
www.firesafe.org- but of course you will know all about that Tom!