A fire in the middle of the room has fresh air all around it ie for 360degrees, so although the fire burns well, the rising plume easily entrains more air. This dilutes the hot gases to slow the rate of temperature rise in the plume. On hitting the ceiling, the spreading plume entrains more air, further limiting the rate at which the temperature rises. Heat is lost to the ceiling over a large area, until the room walls are reached.
But in the corner of a room, air can only get into the plume from a quarter of the circumference of the fire (90deg, which is what SamFIRT meant by his 45deg?). Likewise as it spreads across the ceiling, it is advancing on a more limited circumference which means less air to entrain into it and a smaller ceiling area to lose heat to. So the plume will be hotter and therefore warm things up more quickly. Being at a higher temperature than the unconfined centre of room plume, it is more buoyant and it will spread at a faster rate.