No extinguisher should be used on live electricla circuits. Some AFFF, and indeed water, extinguishers have had the electrical conductivity test and are marked as being safe for ACCIDENTAL use on live circuits., bu this is by extinbguisher manufacturer and nothing to do with a generic type. So it is not possible to say that AFFF extinguihsers are, or are nor, safe for use ACCIDENTALLY on live circuits. You must check with each maker, and either way assume that electricity and water mix rather too well and are, therefore, to be kept apart. The basis of the test is to check the conductivity along the spray stream form the live circuit back tot he handle of the extinguisher, however many other variables could be in place at the actual fire, wet floor from usingt he extinguisher and differig footwear, examples that can have as much, if not more effect, than the stream of extinguishant.
You are right about the UK use of water based extinguishers alongside CO2. Powder would do both, but risks the mess and visibility problems that can be avoided by using aqueous extinguishants. How many people think about rendering the hazard and risks of live circuits safer through adoption of RCDs rather than CO2, or ACCIDENTAL use safety of AFFF/Water? Doing so would be far more appropriate.