Hi Yellowjacket
Never having done it I can only estimate that by decanting a tank load of pre-mix in to another vessel and then transferring it back to the appliance later, this will create a certain amount of turbulence, the severity of this will depend on how carefully it is done, but this will cause some foaming to occur increasing the volume but essentially decreasing the liquid content. Instinctively I wouldn't recommend it although I have no scientific facts to base that on.
The matter of using up good foam for training is a major cost factor to smaller operators, what we try to do is combine many functions when we decide to take the plunge and empty the tank,i.e. in addition to carrying out an exercise, do some drills first, then standard test the hose and test the foam quality on a flammable liquid fire, in a nutshell get as much value as possible from the tank capacity. There is an option in purchasing training foam but its not that much cheaper and you would need to empty the tank to apply the training foam anyway so it isn't a practical option.
The best thing is to plan your training program, estimate foam usage from the modules that involve the need for it and budget for it. Unfortunately if your budget doesn't meet this estimated cost you may end up like a lot of smaller operators and have the training program dictated by cost rather than the other way around.