Ok, It's late and I have nothing better to do.
Who did the maths?
Some bloke named Gunnar Heskestad I think.
Why 5.54, ¼ and -3/8 ?
Because that is what that clever bloke named Heskestad found.
By whom?
James A. Milke in the SFPE Handbook, but I believe that the main credit should go to Heskestad.
(Especially since the SFPE handbook seems to have an error as it is
-3.8 in there, not
-3/8.)
Also. How does the formula take into account the fuel type and therefore the HSG type being produced? How does it take into account the efficiency of combustion and whether the fire is burning in fuel or ventilation controlled conditions?
First of all, forgive me if I am being stupid but I have no idea what you mean by HSG.
It clearly does not concern itself with the fuel type, fuel amount or efficiency, All of those things would help to determine Q.
A useful analogy here would be as follows:
[Conversation in a pub]
Sam's mate: I worked out that my car does about 50mpg
Sam: But you would need to know about the aerodynamics of the car, the octance of the fuel, the rolling resistance, the weight carried in the car and loads of other things!
Sam's mate: No, I just filled it up, then the next time I filled it up, looked how many miles I had done and looked at how many gallons it took to fill up, divided the miles by the gallons, and it came to 50.
Sam: But what about when it is cold petrol doesn't burn as efficiently, surely you had to calculate that?
Sam's mate: No mate.
Sam: What about other loads, like having the air-con on? That alters the fuel consumption too!
Sam's mate: It does 50mpg on average, I worked it out.
Sam: But what about air pressure? What about the weight difference as you use more fuel?
Sam's mate: I am going home.
Sam: In your car?
Sam's mate: Yes.
Sam: Don't believe your sat-nav.
Sam's mate: Why?
Sam: Because Heisenberg's uncertainty principle proves that there is no way that a sat-nav can actually know where you are AND the speed you are going!
Sam's mate: I think I need some new friends.
Anyway..... The equation is usually used for smoke calculations in shopping malls and atria, the types of places where stratification could be a problem, therefore the required inlet air is calculated so ventilation controlled fires are not a problem. If you have a ventilation controlled fire then stratification is probably less of a problem than unburnt gases. And rather than force everyone to calculate stuff from first principles, some kind people such as Mr Milke and Mr Heskestad sometimes try to simplify things for us common people.
Final question (for today) how does it relate to smouldering. Either in totality or pre or post flaming?
It doesn't.
To be honest, if you are asleep in a room with such a slow burning fire, which never reaches a detector, and it kills you, I am afraid that you have just been very very unlucky.