I don't think you will find definitive advice from the official bodies Jasper. I hope you do but I predict their line will be that upgrades of existing door sets are untested and therefore a step in the dark.
Presumably this came about as part of a recommended upgrade to install smoke seals where previously none existed. Whilst perfectly effective retro fit smoke seals are available that fit in the frame ( eg bat wings) presumably the contractor has just gone out to the builders merchant and bought standard combined seals.
I believe best practice advice supported by ASDMA et al in such a case is that if the FD30 door remains a good close fit in its frame and closes effectively then it is still fit for purpose. They will say that the consequence of carrying out upgrades retrospectively is completely untested and unpredictable. However such an approach will not meet the approval of many enforcers in the industry, or many fire risk assessors. I think there is a specific determination on this on the HMG website.
On the other hand there are proprietary seals available on the market and some have specific fire test certificates and some of these claim to be able to overcome many of the problems we assessors encounter in the real world, including compensation for excessive door / frame gaps. You and I know only too well that sometimes we assessors have to make judgements in the field and may use such products, just as we make compromises in heritage buildings, always taking into account the full circumstances of the case.
As for the double seals I wager that nobody will have seen or tested the consequences of this. So much will depend on the fire, the type of seal and where they sit in relation to each other. You could speculate that 25mm doorstops will exacerbate the problem- but speculation is all it would be.
I will hold my hand up to similar upgrades in the past, but usually I have recommended that the old seal be removed and the gap in filled with a hardwood fillet though workmanship is critical. I know that this will attract concern from the door industry but remember sometimes this work has been a requirement of an enforcement notice.