Once again with the Scottish perspective, like the RR(FS)O the Fire (Scotland) Act and the Fire Safety (Scotland) Regulations 'shall bind the Crown'.
Enforcement in Scotland in Crown premises is by Enforcement Officers from HM Inspectorate of Scottish Fire & Rescue Services. Enforcement is done by Notices, Alterations Notices and reference to the Court of Session (in the final instances).
With regard to standards of cover the automatic fire detection systems are equivalent (in Scottish Prisons) to a M/L1 coverage, every cell, every room, every space bigger than a biscuit tin. Emergency lighting is to BS 5266, signage follow the BS 5499 series etc. etc.
As for smoking, Prisoners are permitted to smoke in their cells (considered on legal advice to be their domicile) but is prohibited everywhere else and for everyone else.
For security / operational reasons some fire safety provisons have to be 'restricted', e.g. access to extinguishers, hosereels and even (occasionally) manual operating points for the fire alarm system.
Evacuation drills involving prisoners need careful consideration as do trainng exercise for the local F&RS ops crews.
Happy to discuss further by direct e-mail if fire safety in Prisons is of interest.