Well done Steve_gb you nearly remembered. To extend the pipework of a VESDA detector you should use the ASPIRE software program to ensure that the detector will work to the required sensitivity and timings. Thats the correct and responsible way of doing it.
Here's some rules of thumb though. A VESDA LaserPLUS (VLP) has four pipes but does not distinguish between which pipe detects the smoke. Each pipe could cover the return air grilles, known as primary detection, the room space or voids, known as secondary detection or be installed with a sampling point into each cabinet, known as cabinet protection.
If all four pipes are used, each pipe can be a maximum of 50m in length. If only two pipes are used each pipe could be 100m in length. For room detection hole spacing should be 5m apart (BS6266) or 10m apart (BS5839).
To answer the question above, assuming that the addition of an extra cabinet means that it is cabinet protection that is being implemented, as long as the pipework is under 50m in length and any capillaries used are under 2m in length, and as long as there are no more than 10 holes in a 50m length of pipe you will probably find that adding one aditional hole will not create any problems.
If it does create a problem it will probably be that it affects the flow rate which will more than likely only reduce transport time from the end hole. This could be corrected by increasing the fan speed of the detector. Sensitivity can also be easily adjusted to take account of the extra hole (although i suspect this would not be required)
You may also find that if the transport time is increased it is still within parameters. BS allows for a max of 120 secs for the transport time. Xtralis, the manufacturers of VESDA, recommend 60 secs. You will probably find that the origional calcs were done to meet this 60 sec target and therefore an additional hole wouldn't make much difference.
Or you may find, as suggested above, that it was done by cowboys in which case none of the above applies and you should just add your extra hole anyway.