Wee Brian, as requested a response about prison cells. (and I'll try to give as much information as I can within the sensitivity of this discussion)
You are absolutely right about the fire load. The cells are provided with fire retardant mattresses and bedding (although some of the bedding can be outwith the standards). The huge fire load components come from the Prisoner's possessions, which include clothing, electrical items, and paper in the form of books and magazines. However quantities of free burning accelerants is severly limited through routine checks.
We have a tiny number of fires outside cells. We have a fair number in cells. Only a very limited number of these in-cell fires have an 'accidental cause'
Our watermist system was fully tested by a third party fire engineering company, by building a portion of a cell wing in a test facility, establishing a test fire load using 'real' materials which could be replicated for subsequent tests, and setting up a test recording process which would record temperatures, toxin levels (HCN, HCl & CO) at 9 points in the cell.
The test outcomes were measured against pre-determined tenability criteria to ensure that post ignition the fire did not cross a life threatening threshold within the cell before or after the watermist system operated. These tenability criteria included a maximum CO value (measured in parts / million) and a maximum teperature at head height (the prisoners head and not the watermist head) of 60 degs C.
The system passed the series of tests although the the CO generation did edge towards the criteria limits. The happy news is that post operation the temparture curves from all 9 sensors fell off almost vertically. Toxin recorders also showed a remarkable decline in the toxins due to the effect of the mist.
It was these test which woke us up to the actual quantities of CO which are produced during a fire in a cell. so, where watermist is not installed we now use in cell systems such as CO detection, aspirating sytems (far too prone to induced false alarms) and optical detectors.
As for ventilation, there is a 3 mm gap all the way around the door and a window opening which is actually an air opening rather that the accpeted sense of an open window. Cells are not air conditioned, and the only ventialtion ducts available are foul air exchangers from the toilet facilities.