Smoke clearance is exactly what it says. It is to clear the smoke after the fire is out. But, in large spaces, it can be very difficult, due to smoke logging, for fire fighters to find the fire, let alone put it out or conduct searches of the building. So they might want to ventilate the space during the fire fighting operations using the smoke clearance facilities provided.
The figures, frankly, could be plucked out the air. Equally as important as the area of ventilation are the wind conditions, yet the standard, wisely, makes no requirement on wind conditions at the time of the fire! Like many figures in ADB and 9999 the figures have an arbitrary nature to them but they are trusted and re-used and up-held because they have been around a long time and because they have stood the test of time over that period. They're not always going to be right but what would you recommend replacing them with?
As well as smoke clearance there is also smoke control and this is more commonly used during the fire to maintain safe means of escape, to protect the structure and, possibly, to assist fire fighting. This is more complex and less arbitrary.
Stu