Nearlythere - I am assuming the inward opening door cannot adjusted to open in the direction of escape. My notes from the college say that you can still have 100 in the room because the width allows it; the separate rule being that doors are to open in the direction of escape. My question is, if you can't adjust the door can you still have 100 or are you limited to 60?
According to practically all guidance you are limited to 60 for an inward opening door. However, in this age of risk assessment over prescriptive FS measures you could consider an increase if the risk in the room is low and that the adequacy of the means of escape, via an inward opening door, would not be compromised so as to constitute a risk to the users.
This could depend on the nature of the occupiers and the fire risk in the room. You could argue that the behaviour of staff in a fire situation would be much different to that from members of the public, the former, through fire awareness training, expected to more calm and composed during an evacuation.
Additionally, if the fire risk in the room is much lower than normal you could equally argue that the need to evacuate the room within the usually recommended 2 - 3 minutes could be extended as occupiers waiting to leave the room would not be at risk until much longer.
Of course the fire may not be in that room and if it was elsewhere factors relating to other parts of the building would have to be taken in to considered.