Motorbikes generally used miniature CBM extinguishers such as the 'Presto'. police motorbikes used to bracket BCF extinguishers to the pannier.
If you have got a tight footwell I would agree it can be awkward - the boot is viable as long as it is bracketed in a place that is not easily obstructed - too many are just chucked in the back and get buried under junk.
2 litre/kilo extinguisher is around 400mm H x 110mm dia
I've seen a lot of footage of car fires and you have to be very quick and good to get it with anything less than 2 kilo - it's all down to how fast you notice it.
'Four by two' relates to the technique developed in the UK for dealing with Motorsport fires by track marshals. You have a team of four marshals, two with a 9 kilo Powder extinguisher (ideally Monnex or Purple K, but this is now rare due to cost) and two with 9 litre Air Foam branchpipe extinguishers (now AFFF Spray).
As you have in effect a shielded fire to prevent flash back and chasing the fire in circles the two powders go in first from different sides to give rapid knockdown to protect the driver.
However as powder offers no burn back resistance the two foams follow behind laying a blanket on the spill and cooling the structure of the vehicle.
This way even if the powders don't get it all out you have a vastly reduced fire due to the partial foam blanket and even if you do put it out you don't have to worry about reignition.
The problem with relying just on powder and to why you need good live fire training if you are relying on a first aid attack for life safety in high risk situations is graphically illustrated here in the Paletti crash of 1982;
http://www.youtube.com/watch?v=Gmz9_FdWD5c&feature=relatedAlthough the impact injuries were the primary cause of death, the fire didn't help and it is alleged that the large quantities of powder (from my reckoning nearly 100kilo) didn't help (although not toxic the finely divided powder is not a good thing to breath in when you have chest and lung injuries)