Don’t forget there are three types of explosion, mechanical, chemical and nuclear. It’s not the last and don’t forget for it to be the second there has to be the correct mix of fuel to oxygen and an ignition source; or the fuel reaching its auto ignition temperature.
Tyre blowouts are usually mechanical explosions. Those experienced on the move are usually caused by either overheating, usually caused by under-inflation, or tyre damage, (usually to the tyre wall) or both. Think about it; the person that runs on underinflated tyres is probably the person that clips curbs and thinks nothing of it. The blowout is usually just a mechanical explosion similar to the overheating of any pressure vessel.
However, an under-inflated tyre can heat to the point of smoulder. This can occur to the inside of the tyre as there is a ready supply of oxygen inside (especially for tubeless tyres as the tube would burst early in the process). This can lead to degradation of the tyre wall from the inside leading to an explosive transition to flame when the tyre wall bursts. This can occur on the move or some while after the vehicle has parked up.
Morel of the story…. run your vehicle tyres on the correct tyre pressures and check their condition.